Which continuous mixers are suitable for detergent formulations with liquid additives?
In the continuous production of detergent powders and granulates, liquid components such as non-ionic surfactants, perfume oils, defoamers, polymer solutions or binders are incorporated into a solid mixture. Enzymes, bleaching agents, optical brighteners and fragrances are often dosed only after energy- or temperature-intensive main steps, because moisture, heat and mechanical stress can impair their stability. Enzymes are therefore often used in detergents as protected granulates.
The choice of mixing system depends above all on the liquid quantity and viscosity, the bulk density and flow behaviour of the base powder, the desired granulate structure, the sensitivity of the ingredients, throughput, cleaning requirements and permissible energy input. Also decisive is whether the liquid addition is only intended to achieve even wetting, or whether targeted agglomeration, granulation, coating, drying or cooling is planned.
Continuous ring-layer mixers and ring-layer granulators are particularly suitable for intensive, rapid wetting and agglomeration. The powder is guided by rotating tools along the mixing-chamber wall as a dynamic ring layer; liquid components are sprayed into this moving layer. The high relative movement supports the distribution of small liquid quantities and the formation of granulate. With excessive liquid dosing or excessive mechanical load, however, oversize particles, caking, abrasion or unwanted heating can occur. Ring-layer systems are therefore particularly sensible where targeted granulation or densification is to take place alongside mixing.
Continuous ploughshare mixers generate a mechanically fluidised product bed. Liquids can be introduced into the moving powder zone via dosing lances or spray nozzles. They are versatile where a detergent base powder needs to be wetted with liquid surfactants, perfume components or other additives. Additional size-reduction tools can limit local over-wetting and lump formation, but increase the energy input and the mechanical load on the product. They should therefore only be used where the recipe and the desired particle structure require it.
Twin-shaft paddle mixers are suitable for continuous processes with moderate energy input and high circulation performance. Counter-rotating paddle shafts generate an overlapping mixing zone in which dry components and liquid additives can be distributed evenly. They are particularly interesting where sensitive granulates, such as coated enzymes, bleach granulates or fragrance carriers, need to be mixed in as gently as possible. Figures for maximum liquid fractions or throughputs, however, are not generally transferable. They depend on the recipe, viscosity, solids surface, apparatus size and desired product structure and must be checked through trials.
Continuous fluid-bed plants are suitable where liquid addition is to be combined with granulation, drying, cooling or coating. In a fluid bed, particles are fluidised by process air while liquids are applied via nozzles. This allows low-dust, free-flowing granulates to be built up or sensitive components to be given protective coatings. The technology is used, for example, where detergent granulates need to be specifically dried, cooled or coated. The energy demand as well as the requirements for exhaust-air treatment, dust separation and process control are higher than for a pure through-flow mixer.
Vertical continuous mixers or cone-screw mixers can be sensible with very shear-sensitive, dusting or fracture-sensitive components. Their strength lies in gentle homogenisation. For highly viscous liquids, larger liquid quantities or targeted agglomeration, however, they are generally less suitable than more intensive ring-layer, ploughshare or twin-shaft systems. They are therefore more of a specialist solution for final mixtures with a low liquid fraction or for mixing in sensitive dry additives.
For liquid dosing, gravimetric solids feeders and mass-flow-controlled liquid dosing systems are appropriate. With viscous additives, positive-displacement pumps, temperature-controlled lines and heatable nozzles are frequently used. Coriolis instruments can be used to capture and control the liquid mass flow; their selection, installation, calibration and suitability for the respective viscosity must be checked. The spray technology must be designed so that droplet size, spray pattern, throughput and nozzle position match the product stream. Addition that is too coarse or locally concentrated promotes lumps and deposits, while atomisation that is too fine can lead to losses or exhaust-air loading with volatile components.
With fragrances and enzymes, late, controlled post-dosing is often sensible. Perfume oils can be applied to a finished, sufficiently cool base granulate. Enzymes are usually used as granulates or coated granulates so that dust release and activity losses are reduced. Moisture and oxidising bleach chemicals can impair enzyme stability; the dosing sequence, contact time, temperature and water content of the formulation must therefore be specifically defined.
A narrow residence-time distribution helps to better control the homogeneity and contact time of sensitive additives. Its actual width, however, is determined by mixer geometry, fill level, throughput, back-mixing and product properties; it cannot be attributed to a particular mixer type as a matter of course. With frequent recipe or fragrance changes, readily accessible product areas, short residual-discharge times and a matched cleaning procedure are also important in order to limit cross-contamination and downtime.
How amixon® controls continuous mixing with liquid addition in the continuous mixer AMK
The amixon® continuous mixer AMK is designed for continuous mixing tasks with dry, moist and suspended products. It can be used where solids are dosed continuously and, where required, combined with liquids such as surfactants, fragrances, oils, binders or other additives. Whether a liquid can be processed without caking, lump formation or impairment of sensitive components, however, depends on the recipe, viscosity, dosing quantity, droplet size, product temperature, mixing intensity and cleaning concept, and must be checked for the specific application.
When starting up the AMK, the discharge element initially remains closed. The gravimetric dosing units start simultaneously at a low mass flow and align their dosing streams with one another during the settling process. The fill level in the mixer rises continuously. Once approximately half the fill quantity is reached, the mixer drive starts. At a fill level of approximately 80 percent of the usable content, the discharge element opens slowly. This fill level is then held constant while the dosing streams are increased step by step up to the intended mass flow. This start-up strategy is intended to ensure that product is only discharged once sufficient mixing has taken place.
Shut-down is likewise carried out in a controlled manner. The dosing units successively reduce their mass flow and are finally switched off together. The mixer continues to run and empties itself via the discharge element. This procedure can significantly reduce start-up and run-out quantities with inadequate mixing quality. Whether product actually has to be discarded depends on the specific recipe, the homogeneity requirement, the control quality of the dosing and the operator's release strategy.
According to amixon®, the fill level can be set in a range of approximately 10 to 80 percent of the usable content. The residence time is influenced by fill level and throughput and, according to the manufacturer, can be set independently of the rotational speed of the mixing tool. This allows mixing intensity and mean residence time to be adjusted separately within wide limits. The actual residence-time distribution, however, is additionally influenced by product properties, mixer geometry, throughput, back-mixing and liquid addition. It should be verified by measurement or through representative mixing trials, particularly for critical dosing and homogeneity requirements.
The SinConvex® mixing tool generates three-dimensional product movement. Depending on tool design and rotational speed, the AMK can be designed for gentle homogenisation or more intensive de-agglomeration. For liquid additions, the position of the addition point, the distribution of the liquid within the product stream and the coordination of nozzle, conveying technology and mixer operation are decisive. Finely distributed addition into a sufficiently agitated product zone can improve homogeneity and limit local over-wetting. With highly viscous additives, temperature-controlled supply vessels, lines or nozzles may be required.
According to the manufacturer, the AMK can also be operated batch-wise. This mode of operation can be sensible, for example, for product trials, smaller recipe batches, premixes or processes with a different fill-level and residence-time profile. For later continuous operation, the dosing streams of all main and minor components must be stable and reproducible; with low-dosed ingredients a premix may be necessary.
According to amixon®, the size range includes, among others, the AMK 50 with a volumetric flow of approximately 1 to 3 m³/h, up to larger sizes such as the AMK 3000 with approximately 45 to 135 m³/h. These figures are to be understood as apparatus-related guide values. The mass throughput actually achievable depends on bulk density, moisture, flow behaviour, recipe, the required residence time and the mixing task.
For applications in detergent production, the AMK can be used for continuous homogenisation and liquid addition. Fragrances or other sensitive additives are frequently introduced only after particularly energy-intensive or thermal preliminary stages. With enzymes it must be taken into account that moisture, temperature, oxidising bleaching agents and mechanical abrasion can affect stability. Enzymes in detergent powders are therefore often dosed as protected granulates and mixed in under controlled conditions.
According to the manufacturer, the AMK mixing chamber is designed for ATEX Zone 20. Hygienic fittings, inspection openings, low-dead-space discharge elements, seals and cleaning options can be selected project-specifically. Whether a plant meets EHEDG, FDA or 3-A requirements is not determined by the mixer type alone. What is decisive are the chosen design, the product-contact materials, surfaces, seals, cleaning technology and the documented validation of the intended process.